By Newhouse S.
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6 41 B. LE NEINDRE AND B. VODAR o r t o r» so co *—i © oo rCN CN DEFINITION An equation of state is any equation which connects a series of states of matter by a relationship between pressure, volume and temperature. Speci fically: 29 B. LE NEINDRE AND B. VODAR For a perfect gas (any gas at a pressure sufficiently low to render its properties essentially indistinguishable from those which it would have at zero pressure) we have pV = nRT (3) where n is the amount of substance. B. V I R I A L C O E F F I C I E N T S Virial coefficients are the coefficients in the expansion of the compressi bility factor pV of an imperfect gas in powers of the density l/V pV = RT[1 + B{V)/V + C(V)/V2 - - - ] (4) or in powers of the pressure p pV=RT[l+Bip)p + C{p)p2 + ---l (5) The density expansion is the more fundamental of the two. C r t O S os^soyitooopsWH-© oooovipo*opK»yi i u w l - ^ ò l o ' - ^ a i b bo©boî-*ol/»bobo K ) N ) t O K ) K ) W W W )W 4i. * . -~j — CTsO^^-^i I I I I I I I I I I μ _ . ρ*«ο^ο>>-'σΝ^οο<-'·ιο >^οο·ο^ο\ΐ7ΐυιυι^ . > t ©O 0O O© OWN Ol O© ^0Q0W ©M yOO OO UO v> l 0N 0J O0 s©U 0iH* A© W< W88 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 S 8 8 8 8 8 8 8 £ 8 8 8 8 8 8 8 I I I I I I I I I I Μ Μ ΐ ο υ ι ο ω ω ^ ^ υ ι I I I I ►— ye o\ w oo yi M p M >i io L f t V O K ) - J O O w v JM W « j bs ΙΛ ^J to In bs Ö Ö to in '«o Ôo M vo M *>4 « 4s» ^J KJ Ò "*- Os SO i-Λ SO SO "*»» 00 SO j ^ .
