By Gerald H. Meier
An available but rigorous dialogue of the thermodynamics of surfaces and interfaces, bridging the distance among textbooks and complex literature via supplying a complete consultant with no an overpowering quantity of arithmetic. The publication starts with a evaluate of the suitable points of the thermodynamics of bulk structures, through an outline of the thermodynamic variables for surfaces and interfaces. very important floor phenomena are targeted, together with wetting, crystalline platforms (including grain boundaries), interfaces among diversified levels, curved interfaces (capillarity), adsorption phenomena and adhesion of floor layers. The later chapters additionally function case reviews to demonstrate real-world functions. every one bankruptcy features a set of research difficulties to enhance the reader's knowing of vital recommendations. excellent as an auxiliary textual content for college kids and a self-study advisor for practitioners and educational researchers operating throughout a large variety of fabrics.
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Additional resources for Thermodynamics of Surfaces and Interfaces: Concepts in Inorganic Materials
Example text
It is adsorbed (n SB > 0). It is clear that, for different concentration profiles, n SB could be positive, negative or zero. The phenomena of adsorption and desorption will be described in detail in Chapter 7. In describing the properties of surfaces it is generally useful to normalize them to unit area of surface. 5) and where A is the area of the interface. These quantities are also called surface excesses. 2 thermodynamic properties 43 The dividing surface can also be used to define the thermodynamic properties of the surface/interface.
3] C. H. P. Lupis, Chemical Thermodynamics of Materials (New York: Elsevier, 1983). [4] R. T. DeHoff, Thermodynamics in Materials Science, 2nd edn. (New York: Taylor and Francis, 2006). [5] M. Hillert, The uses of Gibbs free energy–composition diagrams. , ed. H. I. Aaronson (Warrendale, PA: The Minerals, Metals and Materials Society, 1999), pp. 1–33. [6] A. D. Pelton and H. Schmalzried, On the geometrical representation of phase equilibria, Metall. , 4 (1973), 1395–1404. [7] M. Hillert, Phase Equilibria, Phase Diagrams and Phase Transformations, 2nd edn.
B) Calculate the heat evolved per mole of Cu oxidized when pure O2 is blown through the bath described in (a). Au does not oxidize. The standard enthalpy of formation of Cu2 O is ◦ H1,323K = –318,425 J/mole. 5. An alloy containing 10 atom percent Ni and 90 atom percent Au is a solid solution at 700 °C. It is found that the solution reacts with water vapor to form NiO. 35 volume percent hydrogen with the remainder being water vapor. Calculate (a) aNi , (b) γ Ni , and (c) G¯ M Ni for this alloy.
