By Peter Atkins, Julio de Paula, Ron Friedman

Beginning with quantum mechanics, introducing statistical mechanics, and progressing via to thermodynamics, this new textual content for the two-semester actual chemistry direction includes a wealth of recent functions and insights, in addition to new Mathematical Background inter-chapters to assist scholars overview key quantitative concepts.

"This is a fabulous publication. actual to the authors' philosophy as defined within the preface, it techniques actual chemistry by way of first constructing the quantum concept of molecular digital constitution, then by way of statistical arguments strikes into thermodynamics, and thence to kinetics."

- Peter Taylor, assessment in Chemistry World (Royal Society of Chemistry), July 31, 2009.

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Additional resources for Quanta, Matter and Change: A Molecular Approach to Physical Chemistry

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2(b) Express the typical ground-state electron configuration of an atom of an element in (a) Group 3, (b) Group 5, (c) Group 13 of the periodic table. 3(a) Identify the oxidation numbers of the elements in (a) MgCl2, (b) FeO, (c) Hg2Cl2. Identify the oxidation numbers of the elements in (a) CaH2, (b) CaC2, (c) LiN3. 4(a) Where in the periodic table are metals and nonmetals found? 4(b) Where in the periodic table are transition metals, lanthanoids, and actinoids found? (c) P4. 2(b) (c) N3−. Draw the Lewis (electron dot) structures of (a) SO2− 3 , (b) XeF4, Draw the Lewis (electron dot) structures of (a) O3, (b) ClF +3 , Summarize the principal concepts of the VSEPR theory of molecular shape.

The velocity and position are vectors, with both direction and magnitude. The magnitude of the velocity is the speed, v. 13) Like the velocity vector, the linear momentum vector points in the direction of travel of the particle (Fig. 8); its magnitude is denoted p. 14a) For motion confined to one dimension, we would write dpx /dt = Fx. 14a may be taken as the definition of force. 14b) where a is the acceleration of the particle, its rate of change of velocity. 14 will give the trajectory, the position and momentum of the particle at each instant.

The Taylor series for a function f(x) in the vicinity of x = a is ⎛ df ⎞ 1 ⎛ d2 f ⎞ f (x) = f (a) + ⎜ ⎟ (x − a) + ⎜⎜ 2 ⎟⎟ (x − a)2 2 ! ⎝ dx ⎠ a ⎝ dx ⎠ a +$ + = ∞ 1 ⎛ dn f ⎞ ⎜ ⎟ (x − a)n + $ n ! ⎜⎝ dx n ⎟⎠ a 1 ⎛ dn f ⎞ ∑ n! ⎜⎜⎝ dx n ⎟⎟⎠ (x − a)n n= 0 e x = 1 + x + 12 x 2 + $ = ∞ xn n=0 n ! 7c) n =1 Taylor series are used to simplify calculations, for when x << 1 it is possible, to a good approximation, to terminate the series after one or two terms. 8c) A series is said to converge if the sum approaches a finite, definite value as n approaches infinity.

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